Digestive enzymes are those that can break down food materials into utilizable units. They can be taken with food or on an empty stomach to create a systemic effect. Systemic enzymes are taken on an empty stomach as digestion will interfere with their effectiveness.
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These enzymes have very specific functions such as the removal of fibrin build up in the body etc. If you use Massyzmes on an empty stomach, they exert a systemic enzyme effect. Therefore, Masszymes can be used as both a digestive and systemic enzyme.